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titanium isopropoxide : ウィキペディア英語版
titanium isopropoxide

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Titanium isopropoxide, also commonly referred to as titanium tetraisopropoxide or TTIP, is a chemical compound with the formula Ti4. This alkoxide of titanium(IV) is used in organic synthesis and materials science. It is a diamagnetic tetrahedral molecule.
The structures of the titanium alkoxides are often complex. Crystalline titanium methoxide is tetrameric with the molecular formula Ti4(OCH3)16.〔see Wright D. A.; Williams, D. A. “The Crystal and Molecular Structure of Titanium Tetramethoxide” Acta Crystallographica 1968, Volume B24, pages 1107-1114. 〕 Alkoxides derived from bulkier alcohols such as isopropanol aggregate less. Titanium isopropoxide is mainly a monomer in nonpolar solvents.〔Bradley, D. C.; Mehrotra, R.; Rothwell, I.; Singh, A. “Alkoxo and Aryloxo Derivatives of Metals” Academic Press, San Diego, 2001. ISBN 0-12-124140-8.〕
==Preparation==
It is prepared by treating titanium tetrachloride with isopropanol. Hydrogen chloride is formed as a coproduct:〔
:TiCl4 + 4 (CH3)2CHOH → Ti4 + 4 HCl

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